Wash. Admin. Code § 173-340-900

Current through Register Vol. 24-09, May 1, 2024
Section 173-340-900 - Tables

Table 708-1: Toxicity Equivalency Factors for Chlorinated dibenzo-p-dioxins and Chlorinated Dibenzofurans Congeners

CAS Number

Hazardous Substance

Toxicity Equivalency Factor (unitless)(1)

Dioxin Congeners

1746-01-6

2,3,7,8-Tetrachloro dibenzo-p-dioxin

1

40321-76-4

1,2,3,7,8-Pentachloro dibenzo-p-dioxin

1

39227-28-6

1,2,3,4,7,8-Hexachloro dibenzo-p-dioxin

0.1

57653-85-7

1,2,3,6,7,8-Hexachloro dibenzo-p-dioxin

0.1

19408-74-3

1,2,3,7,8,9-Hexachloro dibenzo-p-dioxin

0.1

35822-46-9

1,2,3,4,6,7,8-Heptachloro dibenzo-p-dioxin

0.01

3268-87-9

1,2,3,4,6,7,8,9-Octachloro dibenzo-p-dioxin

0.0003

Furan Congeners

51207-31-9

2,3,7,8-Tetrachloro dibenzofuran

0.1

57117-41-6

1,2,3,7,8-Pentachloro dibenzofuran

0.03

57117-31-4

2,3,4,7,8-Pentachloro dibenzofuran

0.3

70648-26-9

1,2,3,4,7,8-Hexachloro dibenzofuran

0.1

57117-44-9

1,2,3,6,7,8-Hexachloro dibenzofuran

0.1

72918-21-9

1,2,3,7,8,9-Hexachloro dibenzofuran

0.1

60851-34-5

2,3,4,6,7,8-Hexachloro dibenzofuran

0.1

67562-39-4

1,2,3,4,6,7,8-Heptachloro dibenzofuran

0.01

55673-89-7

1,2,3,4,7,8,9-Heptachloro dibenzofuran

0.01

39001-02-0

1,2,3,4,6,7,8,9-Octachloro dibenzofuran

0.0003

(1)Source: Van den Berg et al. 2006. The 2005 World Health Organization Re-evaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-like Compounds.

Toxicological Sciences 2006 93(2):223-241; doi:10.1093/toxsci/kfl055.

Table 708-2: Toxicity Equivalency Factors for Minimum Required

Carcinogenic Polyaromatic Hydrocarbons (cPAHs) under WAC 173-340-708(e)

CAS Number

Hazardous Substance

TEF (unitless)(1)

50-32-08

benzo[a]pyrene

1

56-55-3

benzo[a]anthracene

0.1

205-99-2

benzo[b]fluoranthene

0.1

207-08-9

benzo[k]fluoranthene

0.1

218-01-9

chrysene

0.01

53-70-3

dibenz[a, h]anthracene

0.1

193-39-5

indeno[1,2,3-cd]pyrene

0.1

(1)Source: Cal-EPA, 2005. Air Toxics Hot Spots Program Risk Assessment Guidelines, Part II Technical Support Document for Describing Available Cancer Potency Factors. Office of Environmental Health Hazard Assessment, California Environmental Protection Agency. May 2005.

Table 708-3: Toxicity Equivalency Factors for Carcinogenic Polyaromatic Hydrocarbons (cPAHs) that May be Required under WAC 173-340-708(8)(e)(v)

CAS Number

Hazardous Substance

TEF (unitless)(1)

205-82-3

benzo(j)fluoranthene

0.1

224-42-0

dibenz[a, j]acridine

0.1

226-36-8

dibenz[a, h]acridine

0.1

194-59-2

7H-dibenzo[c, g]carbazole

1

192-65-4

dibenzo[a, e]pyrene

1

189-64-0

dibenzo[a, h]pyrene

10

189-55-9

dibenzo[a, i]pyrene

10

191-30-0

dibenzo[a, l]pyrene

10

3351-31-3

5-methylchrysene

1

5522-43-0

1-nitropyrene

0.1

57835-92-4

4-nitropyrene

0.1

42397-64-8

1,6-dinitropyrene

10

42397-65-9

1,8-dinitropyrene

1

7496-02-8

6-nitrochrysene

10

607-57-8

2-nitrofluorene

0.01

57-97-6

7,12-dimethylbenzanthracene

10

56-49-5

3-methylcholanthrene

1

602-87-9

5-nitroacenaphthene

0.01

(1)Source: Cal-EPA, 2005. Air Toxics Hot Spots Program Risk Assessment Guidelines, Part II Technical Support Document for Describing Available Cancer Potency Factors. Office of Environmental Health Hazard Assessment, California Environmental Protection Agency. May 2005.

Table 708-4: Toxicity Equivalency Factors for Dioxin-Like Polychlorinated Biphenyls (PCBs)

CAS Number

Hazardous Substance

TEF (unitless)(1)

Dioxin-Like PCBs

32598-13-3

3,3',4,4'-Tetrachlorobiphenyl (PCB 77)

0.0001

70362-50-4

3,4,4',5- Tetrachlorobiphenyl (PCB 81)

0.0003

32598-14-4

2,3,3',4,4'-Pentachlorobiphenyl (PCB 105)

0.00003

74472-37-0

2,3,4,4',5-Pentachlorobiphenyl (PCB 114)

0.00003

31508-00-6

2,3',4,4',5-Pentachlorobiphenyl (PCB 118)

0.00003

65510-44-3

2',3,4,4',5-Pentachlorobiphenyl (PCB 123)

0.00003

57465-28-8

3,3',4,4',5-Pentachlorobiphenyl (PCB 126)

0.1

38380-08-4

2,3,3',4,4',5-Hexachlorobiphenyl (PCB 156)

0.00003

69782-90-7

2,3,3',4,4',5'-Hexachlorobiphenyl (PCB 157)

0.00003

52663-72-6

2,3',4,4',5,5'-Hexachlorobiphenyl (PCB 167)

0.00003

32774-16-6

3,3',4,4',5,5'-Hexachlorobiphenyl (PCB 169)

0.03

39635-31-9

2,3,3',4,4',5,5'-Heptachlorobiphenyl (PCB 189)

0.00003

(1)Source: Van den Berg et al. 2006. The 2005 World Health Organization Re-evaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-like Compounds. Toxicological Sciences 2006 93(2):223-241; doi:10.1093/toxsci/kfl055.

Table 720-1

Method A Cleanup Levels for Groundwater.a

Hazardous Substance

CAS Number

Cleanup Level

Arsenic

7440-38-2

5 ug/literb

Benzene

71-43-2

5 ug/literc

Benzo(a)pyrene

50-32-8

0.1 ug/literd

Cadmium

7440-43-9

5 ug/litere

Chromium (Total)

7440-47-3

50 ug/literf

DDT

50-29-3

0.3 ug/literg

1,2 Dichloroethane (EDC)

107-06-2

5 ug/literh

Ethylbenzene

100-41-4

700 ug/literi

Ethylene dibromide (EDB)

106-93-4

0.01 ug/literj

Gross Alpha Particle Activity

15 pCi/literk

Gross Beta Particle Activity

4 mrem/yrl

Lead

7439-92-1

15 ug/literm

Lindane

58-89-9

0.2 ug/litern

Methylene chloride

75-09-2

5 ug/litero

Mercury

7439-97-6

2 ug/literp

MTBE

1634-04-4

20 ug/literq

Naphthalenes

91-20-3

160 ug/literr

PAHs (carcinogenic)

See benzo(a)pyrened

PCB mixtures

0.1 ug/liters

Radium 226 and 228

5 pCi/litert

Radium 226

3 pCi/literu

Tetrachloroethylene

127-18-4

5 ug/literv

Toluene

108-88-3

1,000 ug/literw

Total Petroleum Hydrocarbonsx

[Note: Must also test for and meet cleanup levels for other petroleum components--see footnotes!]

Gasoline Range Organics

Benzene present in groundwater

800 ug/liter

No detectable benzene in groundwater

1,000 ug/liter

Diesel Range Organics

500 ug/liter

Heavy Oils

500 ug/liter

Mineral Oil

500 ug/liter

1,1,1 Trichloroethane

71-55-6

200 ug/litery

Trichloroethylene

79-01-6

5 ug/literz

Vinyl chloride

75-01-4

0.2 ug/literaa

Xylenes

1330-20-7

1,000 ug/literbb

Footnotes:

a

Caution on misusing this table. This table has been developed for specific purposes. It is intended to provide conservative cleanup levels for drinking water beneficial uses at sites undergoing routine cleanup actions or those sites with relatively few hazardous substances. This table may not be appropriate for defining cleanup levels at other sites. For these reasons, the values in this table should not automatically be used to define cleanup levels that must be met for financial, real estate, insurance coverage or placement, or similar transactions or purposes. Exceedances of the values in this table do not necessarily mean the groundwater must be restored to those levels at all sites. The level of restoration depends on the remedy selected under WAC 173-340-350 through 173-340-390.

b

Arsenic. Cleanup level based on background concentrations for state of Washington.

c

Benzene. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ).

d

Benzo(a)pyrene. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ), adjusted to a 1 x 10-5 risk. If other carcinogenic PAHs are suspected of being present at the site, test for them and use this value as the total concentration that all carcinogenic PAHs must meet using the toxicity equivalency methodology in WAC 173-340-708(8).

e

Cadmium. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.62 ).

f

Chromium (Total). Cleanup level based on concentration derived using Equation 720-1 for hexavalent chromium. This is a total value for chromium III and chromium VI. If just chromium III is present at the site, a cleanup level of 100 ug/l may be used (based on WAC 246-290-310 and 40 C.F.R. 141.62 ).

g

DDT (dichlorodiphenyltrichloroethane). Cleanup levels based on concentration derived using Equation 720-2.

h

1,2 Dichloroethane (ethylene dichloride or EDC). Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ).

i

Ethylbenzene. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ).

j

Ethylene dibromide (1,2 dibromoethane or EDB). Cleanup level based on concentration derived using Equation 720-2, adjusted for the practical quantitation limit.

k

Gross Alpha Particle Activity, excluding uranium. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.15 ).

l

Gross Beta Particle Activity, including gamma activity. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.15 ).

m

Lead. Cleanup level based on applicable state and federal law ( 40 C.F.R. 141.80 ).

n

Lindane. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ).

o

Methylene chloride (dichloromethane). Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ).

p

Mercury. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.62 ).

q

Methyl tertiary-butyl ether (MTBE). Cleanup level based on federal drinking water advisory level (EPA-822-F-97-009, December 1997).

r

Naphthalenes. Cleanup level based on concentration derived using Equation 720-1. This is a total value for naphthalene, 1-methyl naphthalene and 2-methyl naphthalene.

s

PCB mixtures. Cleanup level based on concentration derived using Equation 720-2, adjusted for the practical quantitation limit. This cleanup level is a total value for all PCBs.

t

Radium 226 and 228. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.15 ).

u

Radium 226. Cleanup level based on applicable state law (WAC 246-290-310 ).

v

Tetrachloroethylene. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ).

w

Toluene. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ).

x

Total Petroleum Hydrocarbons (TPH). TPH cleanup values have been provided for the most common petroleum products encountered at contaminated sites. Where there is a mixture of products or the product composition is unknown, samples must be tested using both the NWTPH-Gx and NWTPH-Dx methods and the lowest applicable TPH cleanup level must be met.

Gasoline range organics means organic compounds measured using method NWTPH-Gx. Examples are aviation and automotive gasoline. The cleanup level is based on protection of groundwater for noncarcinogenic effects during drinking water use. Two cleanup levels are provided. The higher value is based on the assumption that no benzene is present in the groundwater sample. If any detectable amount of benzene is present in the groundwater sample, then the lower TPH cleanup level must be used. No interpolation between these cleanup levels is allowed. The groundwater cleanup level for any carcinogenic components of the petroleum [such as benzene, EDB and EDC] and any noncarcinogenic components [such as ethylbenzene, toluene, xylenes and MTBE], if present at the site, must also be met. See Table 830-1 for the minimum testing requirements for gasoline releases.

Diesel range organics means organic compounds measured using NWTPH-Dx. Examples are diesel, kerosene, and #1 and #2 heating oil. The cleanup level is based on protection from noncarcinogenic effects during drinking water use. The groundwater cleanup level for any carcinogenic components of the petroleum [such as benzene and PAHs] and any noncarcinogenic components [such as ethylbenzene, toluene, xylenes and naphthalenes], if present at the site, must also be met. See Table 830-1 for the minimum testing requirements for diesel releases.

Heavy oils means organic compounds measured using NWTPH-Dx. Examples are #6 fuel oil, bunker C oil, hydraulic oil and waste oil. The cleanup level is based on protection from noncarcinogenic effects during drinking water use, assuming a product composition similar to diesel fuel. The groundwater cleanup level for any carcinogenic components of the petroleum [such as benzene, PAHs and PCBs] and any noncarcinogenic components [such as ethylbenzene, toluene, xylenes and naphthalenes], if present at the site, must also be met. See Table 830-1 for the minimum testing requirements for heavy oil releases.

Mineral oil means non-PCB mineral oil, typically used as an insulator and coolant in electrical devices such as transformers and capacitors measured using NWTPH-Dx. The cleanup level is based on protection from noncarcinogenic effects during drinking water use. Sites using this cleanup level must analyze groundwater samples for PCBs and meet the PCB cleanup level in this table unless it can be demonstrated that: (1) The release originated from an electrical device manufactured after July 1, 1979; or (2) oil containing PCBs was never used in the equipment suspected as the source of the release; or (3) it can be documented that the oil released was recently tested and did not contain PCBs. Method B (or Method C, if applicable) must be used for releases of oils containing greater than 50 ppm PCBs. See Table 830-1 for the minimum testing requirements for mineral oil releases.

y

1,1,1 Trichloroethane. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ).

z

Trichloroethylene. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ).

aa

Vinyl chloride. Cleanup level based on applicable state and federal law (WAC 246-290-310 and 40 C.F.R. 141.61 ), adjusted to a 1 x 10-5 risk.

bb

Xylenes. Cleanup level based on xylene not exceeding the maximum allowed cleanup level in this table for total petroleum hydrocarbons and on prevention of adverse aesthetic characteristics. This is a total value for all xylenes.

Table 740-1 Method A Soil Cleanup Levels for Unrestricted Land Uses.a

Hazardous Substance

CAS Number

Cleanup Level

Arsenic

7440-38-2

20 mg/kgb

Benzene

71-43-2

0.03 mg/kgc

Benzo(a)pyrene

50-32-8

0.1 mg/kgd

Cadmium

7440-43-9

2 mg/kge

Chromium

Chromium VI

18540-29-9

19 mg/kgf1

Chromium III

16065-83-1

2,000 mg/kgf2

DDT

50-29-3

3 mg/kgg

Ethylbenzene

100-41-4

6 mg/kgh

Ethylene dibromide (EDB)

106-93-4

0.005 mg/kgi

Lead

7439-92-1

250 mg/kgj

Lindane

58-89-9

0.01 mg/kgk

Methylene chloride

75-09-2

0.02 mg/kgl

Mercury (inorganic)

7439-97-6

2 mg/kgm

MTBE

1634-04-4

0.1 mg/kgn

Naphthalenes

91-20-3

5 mg/kgo

PAHs (carcinogenic)

See benzo(a)pyrened

PCB Mixtures

1 mg/kgp

Tetrachloroethylene

127-18-4

0.05 mg/kgq

Toluene

108-88-3

7 mg/kgr

Total Petroleum Hydrocarbonss

[Note: Must also test for and meet cleanup levels for other petroleum components--see footnotes!]

Gasoline Range Organics

Gasoline mixtures without benzene and the total of ethylbenzene, toluene and xylene are less than 1% of the gasoline mixture

100 mg/kg

All other gasoline mixtures

30 mg/kg

Diesel Range Organics

2,000 mg/kg

Heavy Oils

2,000 mg/kg

Mineral Oil

4,000 mg/kg

1,1,1 Trichloroethane

71-55-6

2 mg/kgt

Trichloroethylene

79-01-6

0.03 mg/kgu

Xylenes

1330-20-7

9 mg/kgv

Footnotes:

a

Caution on misusing this table. This table has been developed for specific purposes. It is intended to provide conservative cleanup levels for sites undergoing routine cleanup actions or for sites with relatively few hazardous substances, and the site qualifies under WAC 173-340-7491 for an exclusion from conducting a simplified or site-specific terrestrial ecological evaluation, or it can be demonstrated using a terrestrial ecological evaluation under WAC 173-340-7492 or 173-340-7493 that the values in this table are ecologically protective for the site. This table may not be appropriate for defining cleanup levels at other sites. For these reasons, the values in this table should not automatically be used to define cleanup levels that must be met for financial, real estate, insurance coverage or placement, or similar transactions or purposes. Exceedances of the values in this table do not necessarily mean the soil must be restored to these levels at a site. The level of restoration depends on the remedy selected under WAC 173-340-350 through 173-340-390.

b

Arsenic. Cleanup level based on direct contact using Equation 740-2 and protection of groundwater for drinking water use using the procedures in WAC 173-340-747(4), adjusted for natural background for soil.

c

Benzene. Cleanup level based on protection of groundwater for drinking water use, using the procedures in WAC 173-340-747(4) and (6).

d

Benzo(a)pyrene. Cleanup level based on direct contact using Equation 740-2. If other carcinogenic PAHs are suspected of being present at the site, test for them and use this value as the total concentration that all carcinogenic PAHs must meet using the toxicity equivalency methodology in WAC 173-340-708(8).

e

Cadmium. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4), adjusted for the practical quantitation limit for soil.

f1

Chromium VI. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

f2

Chromium III. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4). Chromium VI must also be tested for and the cleanup level met when present at a site.

g

DDT (dichlorodiphenyltrichloroethane). Cleanup level based on direct contact using Equation 740-2.

h

Ethylbenzene. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

i

Ethylene dibromide (1,2 dibromoethane or EDB). Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4), adjusted for the practical quantitation limit for soil.

j

Lead. Cleanup level based on preventing unacceptable blood lead levels.

k

Lindane. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4), adjusted for the practical quantitation limit.

l

Methylene chloride (dichloromethane). Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

m

Mercury. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

n

Methyl tertiary-butyl ether (MTBE). Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

o

Naphthalenes. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4). This is a total value for naphthalene, 1-methyl naphthalene and 2-methyl naphthalene.

p

PCB Mixtures. Cleanup level based on applicable federal law ( 40 C.F.R. 761.61 ). This is a total value for all PCBs.

q

Tetrachloroethylene. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

r

Toluene. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

s

Total Petroleum Hydrocarbons (TPH). TPH cleanup values have been provided for the most common petroleum products encountered at contaminated sites. Where there is a mixture of products or the product composition is unknown, samples must be tested using both the NWTPH-Gx and NWTPH-Dx methods and the lowest applicable TPH cleanup level must be met.

Gasoline range organics means organic compounds measured using method NWTPH-Gx. Examples are aviation and automotive gasoline. The cleanup level is based on protection of groundwater for noncarcinogenic effects during drinking water use using the procedures described in WAC 173-340-747(6). Two cleanup levels are provided. The lower value of 30 mg/kg can be used at any site. When using this lower value, the soil must also be tested for and meet the benzene soil cleanup level. The higher value of 100 mg/kg can only be used if the soil is tested and found to contain no benzene and the total of ethylbenzene, toluene and xylene are less than 1% of the gasoline mixture. No interpolation between these cleanup levels is allowed. In both cases, the soil cleanup level for any other carcinogenic components of the petroleum [such as EDB and EDC], if present at the site, must also be met. Also, in both cases, soil cleanup levels for any noncarcinogenic components [such as toluene, ethylbenzene, xylenes, naphthalene, and MTBE], also must be met if these substances are found to exceed groundwater cleanup levels at the site. See Table 830-1 for the minimum testing requirements for gasoline releases.

Diesel range organics means organic compounds measured using method NWTPH-Dx. Examples are diesel, kerosene, and #1 and #2 heating oil. The cleanup level is based on preventing the accumulation of free product on the groundwater, as described in WAC 173-340-747(10). The soil cleanup level for any carcinogenic components of the petroleum [such as benzene and PAHs], if present at the site, must also be met. Soil cleanup levels for any noncarcinogenic components [such as toluene, ethylbenzene, xylenes and naphthalenes], also must be met if these substances are found to exceed the groundwater cleanup levels at the site. See Table 830-1 for the minimum testing requirements for diesel releases.

Heavy oils means organic compounds measured using NWTPH-Dx. Examples are #6 fuel oil, bunker C oil, hydraulic oil and waste oil. The cleanup level is based on preventing the accumulation of free product on the groundwater, as described in WAC 173-340-747(10) and assuming a product composition similar to diesel fuel. The soil cleanup level for any carcinogenic components of the petroleum [such as benzene, PAHs and PCBs], if present at the site, must also be met. Soil cleanup levels for any noncarcinogenic components [such as toluene, ethylbenzene, xylenes and naphthalenes], also must be met if found to exceed the groundwater cleanup levels at the site. See Table 830-1 for the minimum testing requirements for heavy oil releases.

Mineral oil means non-PCB mineral oil, typically used as an insulator and coolant in electrical devices such as transformers and capacitors, measured using NWTPH-Dx. The cleanup level is based on preventing the accumulation of free product on the groundwater, as described in WAC 173-340-747(10). Sites using this cleanup level must also analyze soil samples and meet the soil cleanup level for PCBs, unless it can be demonstrated that: (1) The release originated from an electrical device that was manufactured after July 1, 1979; or (2) oil containing PCBs was never used in the equipment suspected as the source of the release; or (3) it can be documented that the oil released was recently tested and did not contain PCBs. Method B must be used for releases of oils containing greater than 50 ppm PCBs. See Table 830-1 for the minimum testing requirements for mineral oil releases.

t

1,1,1 Trichloroethane. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

u

Trichloroethylene. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

v

Xylenes. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4). This is a total value for all xylenes.

Table 745-1 Method A Soil Cleanup Levels for Industrial Properties.a

Hazardous Substance

CAS Number

Cleanup Level

Arsenic

7440-38-2

20 mg/kgb

Benzene

71-43-2

0.03 mg/kgc

Benzo(a)pyrene

50-32-8

2 mg/kgd

Cadmium

7440-43-9

2 mg/kge

Chromium

Chromium VI

18540-29-9

19 mg/kgf1

Chromium III

16065-83-1

2,000 mg/kgf2

DDT

50-29-3

4 mg/kgg

Ethylbenzene

100-41-4

6 mg/kgh

Ethylene dibromide (EDB)

106-93-4

0.005 mg/kgi

Lead

7439-92-1

1,000 mg/kgj

Lindane

58-89-9

0.01 mg/kgk

Methylene chloride

75-09-2

0.02 mg/kgl

Mercury (inorganic)

7439-97-6

2 mg/kgm

MTBE

1634-04-4

0.1 mg/kgn

Naphthalene

91-20-3

5 mg/kgo

PAHs (carcinogenic)

See benzo(a)pyrened

PCB Mixtures

10 mg/kgp

Tetrachloroethylene

127-18-4

0.05 mg/kgq

Toluene

108-88-3

7 mg/kgr

Total Petroleum Hydrocarbonss

[Note: Must also test for and meet cleanup levels for other petroleum components--see footnotes!]

Gasoline Range Organics

Gasoline mixtures without benzene and the total of ethylbenzene, toluene and xylene are less than 1% of the gasoline mixture

100 mg/kg

All other gasoline mixtures

30 mg/kg

Diesel Range Organics

2,000 mg/kg

Heavy Oils

2,000 mg/kg

Mineral Oil

4,000 mg/kg

1,1,1 Trichloroethane

71-55-6

2 mg/kgt

Trichloroethylene

79-01-6

0.03 mg/kgu

Xylenes

1330-20-7

9 mg/kgv

Footnotes:

a

Caution on misusing this table. This table has been developed for specific purposes. It is intended to provide conservative cleanup levels for sites undergoing routine cleanup actions or for industrial properties with relatively few hazardous substances, and the site qualifies under WAC 173-340-7491 for an exclusion from conducting a simplified or site-specific terrestrial ecological evaluation, or it can be demonstrated using a terrestrial ecological evaluation under WAC 173-340-7492 or 173-340-7493 that the values in this table are ecologically protective for the site. This table may not be appropriate for defining cleanup levels at other sites. For these reasons, the values in this table should not automatically be used to define cleanup levels that must be met for financial, real estate, insurance coverage or placement, or similar transactions or purposes. Exceedances of the values in this table do not necessarily mean the soil must be restored to these levels at a site. The level of restoration depends on the remedy selected under WAC 173-340-350 through 173-340-390.

b

Arsenic. Cleanup level based on protection of groundwater for drinking water use, using the procedures in WAC 173-340-747(4), adjusted for natural background for soil.

c

Benzene. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4) and (6).

d

Benzo(a)pyrene. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4). If other carcinogenic PAHs are suspected of being present at the site, test for them and use this value as the total concentration that all carcinogenic PAHs must meet using the toxicity equivalency methodology in WAC 173-340-708(8).

e

Cadmium. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4), adjusted for the practical quantitation limit for soil.

f1

Chromium VI. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

f2

Chromium III. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4). Chromium VI must also be tested for and the cleanup level met when present at a site.

g

DDT (dichlorodiphenyltrichloroethane). Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

h

Ethylbenzene. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

i

Ethylene dibromide (1,2 dibromoethane or EDB). Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4), adjusted for the practical quantitation limit for soil.

j

Lead. Cleanup level based on direct contact.

k

Lindane. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4), adjusted for the practical quantitation limit.

l

Methylene chloride (dichloromethane). Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

m

Mercury. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

n

Methyl tertiary-butyl ether (MTBE). Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

o

Naphthalenes. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4). This is a total value for naphthalene, 1-methyl naphthalene and 2-methyl naphthalene.

p

PCB Mixtures. Cleanup level based on applicable federal law ( 40 C.F.R. 761.61 ). This is a total value for all PCBs. This value may be used only if the PCB contaminated soils are capped and the cap maintained as required by 40 C.F.R. 761.61. If this condition cannot be met, the value in Table 740-1 must be used.

q

Tetrachloroethylene. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

r

Toluene. Cleanup level based on protection of groundwater for drinking water use, using the procedure described in WAC 173-340-747(4).

s

Total Petroleum Hydrocarbons (TPH). TPH cleanup values have been provided for the most common petroleum products encountered at contaminated sites. Where there is a mixture of products or the product composition is unknown, samples must be tested using both the NWTPH-Gx and NWTPH-Dx methods and the lowest applicable TPH cleanup level must be met.

Gasoline range organics means organic compounds measured using method NWTPH-Gx. Examples are aviation and automotive gasoline. The cleanup level is based on protection of groundwater for noncarcinogenic effects during drinking water use using the procedures described in WAC 173-340-747(6). Two cleanup levels are provided. The lower value of 30 mg/kg can be used at any site. When using this lower value, the soil must also be tested for and meet the benzene soil cleanup level. The higher value of 100 mg/kg can only be used if the soil is tested and found to contain no benzene and the total of ethylbenzene, toluene and xylene are less than 1% of the gasoline mixture. No interpolation between these cleanup levels is allowed. In both cases, the soil cleanup level for any other carcinogenic components of the petroleum [such as EDB and EDC], if present at the site, must also be met. Also, in both cases, soil cleanup levels for any noncarcinogenic components [such as toluene, ethylbenzene, xylenes, naphthalene, and MTBE], also must be met if these substances are found to exceed groundwater cleanup levels at the site. See Table 830-1 for the minimum testing requirements for gasoline releases.

Diesel range organics means organic compounds measured using method NWTPH-Dx. Examples are diesel, kerosene, and #1 and #2 heating oil. The cleanup level is based on preventing the accumulation of free product on the groundwater, as described in WAC 173-340-747(10). The soil cleanup level for any carcinogenic components of the petroleum [such as benzene, and PAHs], if present at the site, must also be met. Soil cleanup levels for any noncarcinogenic components [such as toluene, ethylbenzene, xylenes and naphthalenes], also must be met if these substances are found to exceed the groundwater cleanup levels at the site. See Table 830-1 for the minimum testing requirements for diesel releases.

Heavy oils means organic compounds measured using NWTPH-Dx. Examples are #6 fuel oil, bunker C oil, hydraulic oil and waste oil. The cleanup level is based on preventing the accumulation of free product on the groundwater, as described in WAC 173-340-747(10) and assuming a product composition similar to diesel fuel. The soil cleanup level for any carcinogenic components of the petroleum [such as benzene, PAHs and PCBs], if present at the site, must also be met. Soil cleanup levels for any noncarcinogenic components [such as toluene, ethylbenzene, xylenes and naphthalenes], also must be met if found to exceed the groundwater cleanup levels at the site. See Table 830-1 for the minimum testing requirements for heavy oil releases.

Mineral oil means non-PCB mineral oil, typically used as an insulator and coolant in electrical devices such as transformers and capacitors, measured using NWTPH-Dx. The cleanup level is based on preventing the accumulation of free product on the groundwater, as described in WAC 173-340-747(10). Sites using this cleanup level must also analyze soil samples and meet the soil cleanup level for PCBs, unless it can be demonstrated that: (1) The release originated from an electrical device that was manufactured after July 1, 1979; or (2) oil containing PCBs was never used in the equipment suspected as the source of the release; or (3) it can be documented that the oil released was recently tested and did not contain PCBs. Method B or C must be used for releases of oils containing greater than 50 ppm PCBs. See Table 830-1 for the minimum testing requirements for mineral oil releases.

t

1,1,1 Trichloroethane. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

u

Trichloroethylene. Cleanup level based on protection of groundwater for drinking water use, using the procedures described in WAC 173-340-747(4).

v

Xylenes. Cleanup level based on protection of groundwater for drinking water use, using the procedure in WAC 173-340-747(4). This is a total value for all xylenes.

Table 747-1 Soil Organic Carbon-Water Partitioning Coefficient (Koc) Values: Nonionizing Organics.

Hazardous Substance

Koc (ml/g)

ACENAPHTHENE

4,898

ALDRIN

48,685

ANTHRACENE

23,493

BENZ(a)ANTHRACENE

357,537

BENZENE

62

BENZO(a)PYRENE

968,774

BIS(2-CHLOROETHYL)ETHER

76

BIS(2-ETHYLHEXYL)PHTHALATE

111,123

BROMOFORM

126

BUTYL BENZYL PHTHALATE

13,746

CARBON TETRACHLORIDE

152

CHLORDANE

51,310

CHLOROBENZENE

224

CHLOROFORM

53

DDD

45,800

DDE

86,405

DDT

677,934

DIBENZO(a,h)ANTHRACENE

1,789,101

1,2-DICHLOROBENZENE (o)

379

1,4-DICHLOROBENZENE (p)

616

DICHLOROETHANE-1,1

53

DICHLOROETHANE-1,2

38

DICHLOROETHYLENE-1,1

65

trans-1,2 DICHLOROETHYLENE

38

DICHLOROPROPANE-1,2

47

DICHLOROPROPENE-1,3

27

DIELDRIN

25,546

DIETHYL PHTHALATE

82

DI-N-BUTYLPHTHALATE

1,567

EDB

66

ENDRIN

10,811

ENDOSULFAN

2,040

ETHYL BENZENE

204

FLUORANTHENE

49,096

FLUORENE

7,707

HEPTACHLOR

9,528

HEXACHLOROBENZENE

80,000

ALPHA-HCH (ALPHA-BHC)

1,762

-HCH (-BHC)

2,139

-HCH (LINDANE)

1,352

MTBE

11

METHOXYCHLOR

80,000

METHYL BROMIDE

9

METHYL CHLORIDE

6

METHYLENE CHLORIDE

10

NAPHTHALENE

1,191

NITROBENZENE

119

PCB-Arochlor 1016

107,285

PCB-Arochlor 1260

822,422

PENTACHLOROBENZENE

32,148

PYRENE

67,992

STYRENE

912

1,1,2,2,-TETRACHLOROETHANE

79

TETRACHLOROETHYLENE

265

TOLUENE

140

TOXAPHENE

95,816

1,2,4-TRICHLOROBENZENE

1,659

TRICHLOROETHANE -1,1,1

135

TRICHLOROETHANE-1,1,2

75

TRICHLOROETHYLENE

94

o-XYLENE

241

m-XYLENE

196

p-XYLENE

311

Sources:

Except as noted below, the source of the Koc values is the 1996 EPA Soil Screening Guidance: Technical Background Document. The values obtained from this document represent the geometric mean of a survey of values published in the scientific literature. Sample populations ranged from 1-65. EDB value from ATSDR Toxicological Profile (TP 91/13). MTBE value from USGS Final Draft Report on Fuel Oxygenates (March 1996). PCB-Arochlor values from 1994 EPA Draft Soil Screening Guidance.

Table 747-2

Predicted Soil Organic Carbon-Water Partitioning Coefficient (Koc) as a Function of pH: Ionizing Organics.

Hazardous Substance

Koc Value (ml/g)

pH = 4.9

pH = 6.8

pH = 8.0

Benzoic acid

5.5

0.6

0.5

2-Chlorophenol

398

388

286

2-4-Dichlorophenol

159

147

72

2-4-Dinitrophenol

0.03

0.01

0.01

Pentachlorophenol

9,055

592

410

2,3,4,5-Tetrachlorophenol

17,304

4,742

458

2,3,4,6-Tetrachlorophenol

4,454

280

105

2,4,5-Trichlorophenol

2,385

1,597

298

2,4,6-Trichlorophenol

1,040

381

131

Source:

1996 EPA Soil Screening Guidance: Technical Background Document. The predicted Koc values in this table were derived using a relationship from thermodynamic equilibrium considerations to predict the total sorption of an ionizable organic compound from the partitioning of its ionized and neutral forms.

Table 747-3 Metals Distribution Coefficients (Kd).

Hazardous Substance

Kd (L/kg)

Arsenic

29

Cadmium

6.7

Total Chromium

1,000

Chromium VI

19

Copper

22

Mercury

52

Nickel

65

Lead

10,000

Selenium

5

Zinc

62

Source:

Multiple sources compiled by the department of ecology.

Table 747-4 Petroleum EC Fraction Physical/Chemical Values.

Fuel

Fraction

Equivalent

Carbon

Number1

Water

Solubility2

(mg/L)

Mol.

Wt.3

(g/mol)

Henry's

Constant4

(cc/cc)

GFW5

(mg/mol)

Density6

(mg/l)

Soil Organic

Carbon-Water

Partitioning

Coefficient

Koc7 (L/kg)

ALIPHATICS

EC 5 - 6

5.5

36.0

81.0

33.0

81,000

670,000

800

EC > 6 - 8

7.0

5.4

100.0

50.0

100,000

700,000

3,800

EC > 8 - 10

9.0

0.43

130.0

80.0

130,000

730,000

30,200

EC > 10 - 12

11.0

0.034

160.0

120.0

160,000

750,000

234,000

EC > 12 - 16

14.0

7.6E-04

200.0

520.0

200,000

770,000

5.37E+06

EC > 16 - 21

19.0

1.3E-06

270.0

4,900

270,000

780,000

9.55E+09

EC > 21 - 34

28.0

1.5E-11

400.0

100,000

400,000

790,000

1.07E+10

AROMATICS

EC > 8 - 10

9.0

65.0

120.0

0.48

120,000

870,000

1,580

EC > 10 - 12

11.0

25.0

130.0

0.14

130,000

900,000

2,510

EC > 12 - 16

14.0

5.8

150.0

0.053

150,000

1,000,000

5,010

EC > 16 - 21

19.0

0.51

190.0

0.013

190,000

1,160,000

15,800

EC > 21 - 34

28.0

6.6E-03

240.0

6.7E-04

240,000

1,300,000

126,000

TPH COMPONENTS

Benzene

6.5

1,750

78.0

0.228

78,000

876,500

62.0

Toluene

7.6

526.0

92.0

0.272

92,000

866,900

140.0

Ethylbenzene

8.5

169.0

106.0

0.323

106,000

867,000

204.0

Total Xylenes8 (average of 3)

8.67

171.0

106.0

0.279

106,000

875,170

233.0

n-Hexane9

6.0

9.5

86.0

74.0

86,000

659,370

3,410

MTBE10

50,000

88.0

0.018

88,000

744,000

10.9

Naphthalenes

11.69

31.0

128.0

0.0198

128,000

1,145,000

1,191

Sources:

1

Equivalent Carbon Number. Gustafson, J.B. et al., Selection of Representative TPH Fractions Based on Fate and Transport Considerations. Total Petroleum Hydrocarbon Criteria Working Group Series, Volume 3 (1997) [hereinafter Criteria Working Group].

2

Water Solubility. For aliphatics and aromatics EC groups, Criteria Working Group. For TPH components except n-hexane and MTBE, 1996 EPA Soil Screening Guidance: Technical Background Document.

3

Molecular Weight.Criteria Working Group.

4

Henry's Constant. For aliphatics and aromatics EC groups, Criteria Working Group. For TPH components except n-hexane and MTBE, 1996 EPA Soil Screening Guidance: Technical Background Document.

5

Gram Formula Weight (GFW). Based on 1000 x Molecular Weight.

6

Density. For aliphatics and aromatics EC groups, based on correlation between equivalent carbon number and data on densities of individual hazardous substances provided in Criteria Working Group. For TPH components except n-hexane and MTBE, 1996 EPA Soil Screening Guidance: Technical Background Document.

7

Soil Organic Carbon-Water Partitioning Coefficient. For aliphatics and aromatics EC groups, Criteria Working Group. For TPH components except n-hexane and MTBE, 1996 EPA Soil Screening Guidance: Technical Background Document.

8

Total Xylenes. Values for total xylenes are a weighted average of m, o and p xylene based on gasoline composition data from the Criteria Working Group (m = 51% of total xylene; o = 28% of total xylene; and p = 21% of total xylene).

9

n-Hexane. For values other than density, Criteria Working Group. For the density value, Hawley's Condensed Chemical Dictionary, 11th ed., revised by N. Irving Sax and Richard J. Lewis (1987).

10

MTBE.USGS Final Report on Fuel Oxygenates (March 1996).

Table 747-5

Residual Saturation Screening Levels for TPH.

Fuel

Screening Level (mg/kg)

Weathered Gasoline

1,000

Middle Distillates

(e.g., Diesel No. 2 Fuel Oil)

2,000

Heavy Fuel Oils

(e.g., No. 6 Fuel Oil)

2,000

Mineral Oil

4,000

Unknown Composition or Type

1,000

Note:

The residual saturation screening levels for petroleum hydrocarbons specified in Table 747-5 are based on coarse sand and gravelly soils; however, they may be used for any soil type. Screening levels are based on the presumption that there are no preferential pathways for NAPL to flow downward to groundwater. If such pathways exist, more stringent residual saturation screening levels may need to be established.

Table 749-1 Simplified Terrestrial Ecological Evaluation - Exposure Analysis Procedure under WAC 173-340-7492(2)(a)(ii).a

Estimate the area of contiguous (connected) undeveloped land on the site or within 500 feet of any area of the site to the nearest 1/2 acre (1/4 acre if the area is less than 0.5 acre). "Undeveloped land" means land that is not covered by existing buildings, roads, paved areas or other barriers that will prevent wildlife from feeding on plants, earthworms, insects or other food in or on the soil.

1) From the table below, find the number of points corresponding to the area and enter this number in the box to the right.

Area (acres)

Points

0.25 or less

4

0.5

5

1.0

6

1.5

7

2.0

8

2.5

9

3.0

10

3.5

11

4.0 or more

12

2) Is this an industrial or commercial property?

See WAC 173-340-7490(3)(c). If yes, enter a score of 3 in the box to the right. If no, enter a score of 1.

3) Enter a score in the box to the right for the habitat quality of the site, using the rating system shown belowb. (High = 1, Intermediate = 2, Low = 3)

4) Is the undeveloped land likely to attract wildlife? If yes, enter a score of 1 in the box to the right. If no, enter a score of 2. See footnote c.

5) Are there any of the following soil contaminants present:

Chlorinated dibenzo-p-dioxins/dibenzofurans, PCB mixtures, DDT, DDE, DDD, aldrin, chlordane, dieldrin, endosulfan, endrin, heptachlor, benzene hexachloride, toxaphene, hexachlorobenzene, pentachlorophenol, pentachlorobenzene? If yes, enter a score of 1 in the box to the right. If no, enter a score of 4.

6) Add the numbers in the boxes on lines 2 through 5 and enter this number in the box to the right. If this number is larger than the number in the box on line 1, the simplified terrestrial ecological evaluation may be ended under WAC 173-340-7492(2)(a)(ii).

Footnotes:

a

It is expected that this habitat evaluation will be undertaken by an experienced field biologist. If this is not the case, enter a conservative score (1) for questions 3 and 4.

b

Habitat rating system. Rate the quality of the habitat as high, intermediate or low based on your professional judgment as a field biologist. The following are suggested factors to consider in making this evaluation:

Low: Early successional vegetative stands; vegetation predominantly noxious, nonnative, exotic plant species or weeds. Areas severely disturbed by human activity, including intensively cultivated croplands. Areas isolated from other habitat used by wildlife.

High: Area is ecologically significant for one or more of the following reasons: Late-successional native plant communities present; relatively high species diversity; used by an uncommon or rare species; priority habitat (as defined by the Washington department of fish and wildlife); part of a larger area of habitat where size or fragmentation may be important for the retention of some species.

Intermediate: Area does not rate as either high or low.

c

Indicate "yes" if the area attracts wildlife or is likely to do so. Examples: Birds frequently visit the area to feed; evidence of high use by mammals (tracks, scat, etc.); habitat "island" in an industrial area; unusual features of an area that make it important for feeding animals; heavy use during seasonal migrations.

Table 749-2 Priority Contaminants of Ecological Concern for Sites that Qualify for the Simplified Terrestrial Ecological Evaluation Procedure.a

Priority contaminant

Soil concentration (mg/kg)

Unrestricted

land useb

Industrial or

commercial site

METALSC

Antimony

See note d

See note d

Arsenic III

20 mg/kg

20 mg/kg

Arsenic V

95 mg/kg

260 mg/kg

Barium

1,250 mg/kg

1,320 mg/kg

Beryllium

25 mg/kg

See note d

Cadmium

25 mg/kg

36 mg/kg

Chromium (total)

42 mg/kg

135 mg/kg

Cobalt

See note d

See note d

Copper

100 mg/kg

550 mg/kg

Lead

220 mg/kg

220 mg/kg

Magnesium

See note d

See note d

Manganese

See note d

23,500 mg/kg

Mercury, inorganic

9 mg/kg

9 mg/kg

Mercury, organic

0.7 mg/kg

0.7 mg/kg

Molybdenum

See note d

71 mg/kg

Nickel

100 mg/kg

1,850 mg/kg

Selenium

0.8 mg/kg

0.8 mg/kg

Silver

See note d

See note d

Tin

275 mg/kg

See note d

Vanadium

26 mg/kg

See note d

Zinc

270 mg/kg

570 mg/kg

PESTICIDES

Aldicarb/aldicarb sulfone (total)

See note d

See note d

Aldrin

0.17 mg/kg

0.17 mg/kg

Benzene hexachloride (including lindane)

10 mg/kg

10 mg/kg

Carbofuran

See note d

See note d

Chlordane

1 mg/kg

7 mg/kg

Chlorpyrifos/chlorpyrifos-methyl (total)

See note d

See note d

DDT/DDD/DDE (total)

1 mg/kg

1 mg/kg

Dieldrin

0.17 mg/kg

0.17 mg/kg

Endosulfan

See note d

See note d

Endrin

0.4 mg/kg

0.4 mg/kg

Heptachlor/heptachlor epoxide (total)

0.6 mg/kg

0.6 mg/kg

Hexachlorobenzene

31 mg/kg

31 mg/kg

Parathion/methyl parathion (total)

See note d

See note d

Pentachlorophenol

11 mg/kg

11 mg/kg

Toxaphene

See note d

See note d

OTHER CHLORINATED ORGANICS

Chlorinated dibenzofurans (total)

3E-06 mg/kg

3E-06 mg/kg

Chlorinated dibenzo-p-dioxins (total)

5E-06 mg/kg

5E-06 mg/kg

Hexachlorophene

See note d

See note d

PCB mixtures (total)

2 mg/kg

2 mg/kg

Pentachlorobenzene

168 mg/kg

See note d

OTHER NONCHLORINATED ORGANICS

Acenaphthene

See note d

See note d

Benzo(a)pyrene

30 mg/kg

300 mg/kg

Bis (2-ethylhexyl) phthalate

See note d

See note d

Di-n-butyl phthalate

200 mg/kg

See note d

PETROLEUM

Gasoline Range Organics

200 mg/kg

12,000 mg/kg except that the concentration shall not exceed residual saturation at the soil surface.

Diesel Range Organics

460 mg/kg

15,000 mg/kg except that the concentration shall not exceed residual saturation at the soil surface.

Footnotes:

a

Caution on misusing these chemical concentration numbers. These values have been developed for use at sites where a site-specific terrestrial ecological evaluation is not required. They are not intended to be protective of terrestrial ecological receptors at every site. Exceedances of the values in this table do not necessarily trigger requirements for cleanup action under this chapter. The table is not intended for purposes such as evaluating sludges or wastes.

This list does not imply that sampling must be conducted for each of these chemicals at every site. Sampling should be conducted for those chemicals that might be present based on available information, such as current and past uses of chemicals at the site.

b

Applies to any site that does not meet the definition of industrial or commercial.

c

For arsenic, use the valence state most likely to be appropriate for site conditions, unless laboratory information is available. Where soil conditions alternate between saturated, anaerobic and unsaturated, aerobic states, resulting in the alternating presence of arsenic III and arsenic V, the arsenic III concentrations shall apply.

d

Safe concentration has not yet been established. See WAC 173-340-7492(2)(c).

Table 749-3

Ecological Indicator Soil Concentrations (mg/kg) for Protection of Terrestrial Plants and Animalsa. For chemicals where a value is not provided, see footnote b.

Note: These values represent soil concentrations that are expected to be protective at any MTCA site and are provided for use in eliminating hazardous substances from further consideration under WAC 173-340-7493(2)(a)(i). Where these values are exceeded, various options are provided for demonstrating that the hazardous substance does not pose a threat to ecological receptors at a site, or for developing site-specific remedial standards for eliminating threats to ecological receptors. See WAC 173-340-7493(1)(b)(i), 173-340-7493(2)(a)(ii) and 173-340-7493(3).

Hazardous Substanceb

Plantsc

Soil biotad

Wildlifee

METALSf:

Aluminum (soluble salts)

50

Antimony

5

Arsenic III

7

Arsenic V

10

60

132

Barium

500

102

Beryllium

10

Boron

0.5

Bromine

10

Cadmium

4

20

14

Chromium (total)

42g

42g

67

Cobalt

20

Copper

100

50

217

Fluorine

200

Iodine

4

Lead

50

500

118

Lithium

35g

Manganese

1,100g

1,500

Mercury, inorganic

0.3

0.1

5.5

Mercury, organic

0.4

Molybdenum

2

7

Nickel

30

200

980

Selenium

1

70

0.3

Silver

2

Technetium

0.2

Thallium

1

Tin

50

Uranium

5

Vanadium

2

Zinc

86g

200

360

PESTICIDES:

Aldrin

0.1

Benzene hexachloride (including lindane)

6

Chlordane

1

2.7

DDT/DDD/DDE (total)

0.75

Dieldrin

0.07

Endrin

0.2

Hexachlorobenzene

17

Heptachlor/heptachlor epoxide (total)

0.4

Pentachlorophenol

3

6

4.5

OTHER CHLORINATED ORGANICS:

1,2,3,4-Tetrachlorobenzene

10

1,2,3-Trichlorobenzene

20

1,2,4-Trichlorobenzene

20

1,2-Dichloropropane

700

1,4-Dichlorobenzene

20

2,3,4,5-Tetrachlorophenol

20

2,3,5,6-Tetrachloroaniline

20

20

2,4,5-Trichloroaniline

20

20

2,4,5-Trichlorophenol

4

9

2,4,6-Trichlorophenol

10

2,4-Dichloroaniline

100

3,4-Dichloroaniline

20

3,4-Dichlorophenol

20

20

3-Chloroaniline

20

30

3-Chlorophenol

7

10

Chlorinated dibenzofurans (total)

2E-06

Chloroacetamide

2

Chlorobenzene

40

Chlorinated dibenzo-p-dioxins (total)

2E-06

Hexachlorocyclopentadiene

10

PCB mixtures (total)

40

0.65

Pentachloroaniline

100

Pentachlorobenzene

20

OTHER NONCHLORINATED ORGANICS:

2,4-Dinitrophenol

20

4-Nitrophenol

7

Acenaphthene

20

Benzo(a)pyrene

12

Biphenyl

60

Diethylphthalate

100

Dimethylphthalate

200

Di-n-butyl phthalate

200

Fluorene

30

Furan

600

Nitrobenzene

40

N-nitrosodiphenylamine

20

Phenol

70

30

Styrene

300

Toluene

200

PETROLEUM:

Gasoline Range Organics

100

5,000 mg/kg except that the concentration shall not exceed residual saturation at the soil surface.

Diesel Range Organics

200

6,000 mg/kg except that the concentration shall not exceed residual saturation at the soil surface.

Footnotes:

a

Caution on misusing ecological indicator concentrations. Exceedances of the values in this table do not necessarily trigger requirements for cleanup action under this chapter. Natural background concentrations may be substituted for ecological indicator concentrations provided in this table. The table is not intended for purposes such as evaluating sludges or wastes.

This list does not imply that sampling must be conducted for each of these chemicals at every site. Sampling should be conducted for those chemicals that might be present based on available information, such as current and past uses of chemicals at the site.

b

For hazardous substances where a value is not provided, plant and soil biota indicator concentrations shall be based on a literature survey conducted in accordance with WAC 173-340-7493(4) and calculated using methods described in the publications listed below in footnotes c and d. Methods to be used for developing wildlife indicator concentrations are described in Tables 749-4 and 749-5.

c

Based on benchmarks published in Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Terrestrial Plants: 1997 Revision, Oak Ridge National Laboratory, 1997.

d

Based on benchmarks published in Toxicological Benchmarks for Potential Contaminants of Concern for Effects on Soil and Litter Invertebrates and Heterotrophic Process, Oak Ridge National Laboratory, 1997.

e

Calculated using the exposure model provided in Table 749-4 and chemical-specific values provided in Table 749-5. Where both avian and mammalian values are available, the wildlife value is the lower of the two.

f

For arsenic, use the valence state most likely to be appropriate for site conditions, unless laboratory information is available. Where soil conditions alternate between saturated, anaerobic and unsaturated, aerobic states, resulting in the alternating presence of arsenic III and arsenic V, the arsenic III concentrations shall apply.

g

Benchmark replaced by Washington state natural background concentration.

Table 749-4 Wildlife Exposure Model for Site-specific Evaluations.a

Plant

KPlant

Plant uptake coefficient (dry weight basis)

Units: mg/kg plant/mg/kg soil

Value: chemical-specific (see Table 749-5)

Soil biota

Surrogate receptor: Earthworm

BAFWorm

Earthworm bioaccumulation factor (dry weight basis)

Units: mg/kg worm/mg/kg soil

Value: chemical-specific (see Table 749-5)

Mammalian predator

Surrogate receptor: Shrew (Sorex)

PSB (shrew)

Proportion of contaminated food (earthworms) in shrew diet

Units: unitless

Value: 0.50

FIRShrew, DW

Food ingestion rate (dry weight basis)

Units: kg dry food/kg body weight - day

Value: 0.45

SIRShrew, DW

Soil ingestion rate (dry weight basis)

Units: kg dry soil/kg body weight - day

Value: 0.0045

RGAFSoil, shrew

Gut absorption factor for a hazardous substance in soil expressed relative to the gut absorption factor for the hazardous substance in food.

Units: unitless

Value: chemical-specific (see Table 749-5)

TShrew

Toxicity reference value for shrew

Units: mg/kg - day

Value: chemical-specific (see Table 749-5)

Home range

0.1 Acres

Avian predator

Surrogate receptor: American robin (Turdus migratorius)

PSB (Robin)

Proportion of contaminated food (soil biota) in robin diet

Unit: unitless

Value: 0.52

FIRRobin, DW

Food ingestion rate (dry weight basis)

Units: kg dry food/kg body weight - day

Value: 0.207

SIRRobin, DW

Soil ingestion rate (dry weight basis)

Units: kg dry soil/kg body weight - day

Value: 0.0215

RGAFSoil, robin

Gut absorption factor for a hazardous substance in soil expressed relative to the gut absorption factor for the hazardous substance in food.

Units: unitless

Value: chemical-specific (see Table 749-5)

TRobin

Toxicity reference value for robin

Units: mg/kg - day

Value: chemical-specific (see Table 749-5)

Home range

0.6 Acres

Mammalian herbivore

Surrogate receptor: Vole (Microtus)

PPlant, vole

Proportion of contaminated food (plants) in vole diet

Units: unitless

Value: 1.0

FIRVole, DW

Food ingestion rate (dry weight basis)

Units: kg dry food/kg body weight - day

Value: 0.315

SIRVole, DW

Soil ingestion rate (dry weight basis)

Units: kg dry soil/kg body weight - day

Value: 0.0079

RGAFSoil, vole

Gut absorption factor for a hazardous substance in soil expressed relative to the gut absorption factor for the hazardous substance in food.

Units: unitless

Value: chemical-specific (see Table 749-5)

TVole

Toxicity reference value for vole

Units: mg/kg - day

Value: chemical-specific (see Table 749-5)

Home range

0.08 Acres

Soil concentrations for wildlife protectionb

(1) Mammalian predator:

SCMP = (TShrew)/[(FIRShrew, DW x PSB (shrew) x BAFWorm) + (SIRShrew, DW x RGAFSoil, shrew)]

(2) Avian predator:

SCAP = (TRobin)/[(FIRRobin, DW x PSB (Robin) x BAFWorm) + (SIRRobin, DW x RGAFSoil, robin)]

(3) Mammalian herbivore:

SCMH = (TVole)/[(FIRVole, DW x PPlant, vole x KPlant) + (SIRVole, DW x RGAFSoil, vole)]

Footnotes:

a

Substitutions for default receptors may be made as provided for in WAC 173-340-7493(7). If a substitute species is used, the values for food and soil ingestion rates, and proportion of contaminated food in the diet, may be modified to reasonable maximum exposure estimates for the substitute species based on a literature search conducted in accordance with WAC 173-340-7493(4).

Additional species may be added on a site-specific basis as provided in WAC 173-340-7493(2)(a).

The department shall consider proposals for modifications to default values provided in this table based on new scientific information in accordance with WAC 173-340-702(14).

b

Use the lowest of the three concentrations calculated as the wildlife value.

Table 749-5 Default Values for Selected Hazardous Substances for use with the Wildlife Exposure Model in Table 749-4.a

Toxicity reference value (mg/kg - d)

Hazardous Substance

BAFWorm

KPlant

Shrew

Vole

Robin

METALS:

Arsenic III

1.16

0.06

1.89

1.15

Arsenic V

1.16

0.06

35

35

22

Barium

0.36

43.5

33.3

Cadmium

4.6

0.14

15

15

20

Chromium

0.49

35.2

29.6

5

Copper

0.88

0.020

44

33.6

61.7

Lead

0.69

0.0047

20

20

11.3

Manganese

0.29

624

477

Mercury, inorganic

1.32

0.0854

2.86

2.18

0.9

Mercury, organic

1.32

0.352

0.27

0.064

Molybdenum

0.48

1.01

3.09

2.36

35.3

Nickel

0.78

0.047

175.8

134.4

107

Selenium

10.5

0.0065

0.725

0.55

1

Zinc

3.19

0.095

703.3

537.4

131

PESTICIDES:

Aldrine

4.77

0.007b

2.198

1.68

0.06

Benzene hexachloride (including lindane)

10.1

7

Chlordane

17.8

0.011b

10.9

8.36

10.7

DDT/DDD/DDE

10.6

0.004b

8.79

6.72

0.87

Dieldrin

28.8

0.029b

0.44

0.34

4.37

Endrin

3.6

0.038b

1.094

0.836

0.1

Heptachlor/heptachlor epoxide

10.9

0.027b

2.857

2.18

0.48

Hexachlorobenzene

1.08

2.4

Pentachlorophenol

5.18

0.043b

5.275

4.03

OTHER CHLORINATED ORGANICS:

Chlorinated dibenzofurans

48

1.0E-05

Chlorinated dibenzo-p-dioxins

48

0.005b

2.2E-05

1.7E-05

1.4E-04

PCB mixtures

4.58

0.087b

0.668

0.51

1.8

OTHER NONCHLORINATED ORGANICS:

Benzo(a)pyrene

0.43

0.011

1.19

0.91

Footnotes:

a

For hazardous substances not shown in this table, use the following default values. Alternatively, use values established from a literature survey conducted in accordance with WAC 173-340-7493(4) and approved by the department.

KPlant:

Metals (including metalloid elements): 1.01

Organic chemicals: KPlant = 10(1.588-(0.578log Kow)),

where log Kow is the logarithm of the octanol-water partition coefficient.

BAFWorm:

Metals (including metalloid elements): 4.6

Nonchlorinated organic chemicals:

log Kow < 5: 0.7

log Kow > 5: 0.9

Chlorinated organic chemicals:

log Kow < 5: 4.7

log Kow > 5: 11.8

RGAFSoil

(all receptors): 1.0

Toxicity reference values (all receptors): Values established from a literature survey conducted in accordance with WAC 173-340-7493(4).

Site-specific values may be substituted for default values, as described below:

KPlant

Value from a literature survey conducted in accordance with WAC 173-340-7493(4) or from empirical studies at the site.

BAFWorm

Value from a literature survey conducted in accordance with WAC 173-340-7493(4) or from empirical studies at the site.

RGAFSoil

(all receptors): Value established from a literature survey conducted in accordance with WAC 173-340-7493(4).

Toxicity reference values (all receptors): Default toxicity reference values provided in this table may be replaced by a value established from a literature survey conducted in accordance with WAC 173-340-7493(4).

b

Calculated from log Kow using formula in footnote a.

Table 830-1

Required Testing for Petroleum Releases.

Gasoline Range Organics (GRO) (1)

Diesel Range Organics (DRO) (2)

Heavy Oils (DRO) (3)

Mineral Oils (4)

Waste Oils and Unknown Oils (5)

Volatile Petroleum Compounds

Benzene

X (6)

X (7)

X (8)

Toluene

X (6)

X (7)

X (8)

Ethyl benzene

X (6)

X (7)

X (8)

Xylenes

X (6)

X (7)

X (8)

n-Hexane

X (9)

Fuel Additives and Blending Compounds

Dibromoethane, 1-2 (EDB); and Dichloroethane, 1-2 (EDC)

X (10)

X (8)

Methyl tertiary-butyl ether (MTBE)

X (11)

X (8)

Total lead other additives

X (12)

X (8)

Other Petroleum Components

Carcinogenic PAHs

X (13)

X (13)

X (8)

Naphthalenes

X (14)

X (14)

X (14)

X (14)

Other Compounds

Polychlorinated Biphenyls (PCBs)

X (15)

X (15)

X (8)

Halogenated Volatile Organic Compounds (VOCs)

X (8)

Other

X (16)

X (16)

X (16)

X (16)

X (16)

Total Petroleum Hydrocarbons Methods

TPH Analytical Method for Total TPH (Method A Cleanup Levels) (17)

NWTPH-Gx

NWTPH-Dx

NWTPH-Dx

NWTPH-Dx

NWTPH-Gx & NWTPH-Dx

TPH Analytical Methods for TPH fractions (Methods B or C) (17)

VPH

EPH

EPH

EPH

VPH and EPH

Use of Table 830-1: An "X" in the box means that the testing requirement applies to groundwater and soil if a release is known or suspected to have occurred to that medium, unless otherwise specified in the footnotes. A box with no "X" indicates (except in the last two rows) that, for the type of petroleum product release indicated in the top row, analyses for the hazardous substance(s) named in the far-left column corresponding to the empty box are not typically required as part of the testing for petroleum releases. However, such analyses may be required based on other site-specific information. Note that testing for Total Petroleum Hydrocarbons (TPH) is required for every type of petroleum release, as indicated in the bottom two rows of the table. The testing method for TPH depends on the type of petroleum product released and whether Method A or Method B or C is being used to determine TPH cleanup levels. See WAC 173-340-830 for analytical procedures. The footnotes to this table are important for understanding the specific analytical requirements for petroleum releases.

Footnotes:

(1) The following petroleum products are common examples of GRO: automotive and aviation gasolines, mineral spirits, stoddard solvents, and naphtha. To be in this range, 90 percent of the petroleum components need to be quantifiable using the NWTPH-Gx; if NWTPH-HCID results are used for this determination, then 90 percent of the "area under the TPH curve" must be quantifiable using NWTPH-Gx. Products such as jet fuel, diesel No. 1, kerosene, and heating oil may require analysis as both GRO and DRO depending on the range of petroleum components present (range can be measured by NWTPH-HCID). (See footnote 17 on analytical methods.)

(2) The following petroleum products are common examples of DRO: Diesel No. 2, fuel oil No. 2, light oil (including some bunker oils). To be in this range, 90 percent of the petroleum components need to be quantifiable using the NWTPH-Dx quantified against a diesel standard. Products such as jet fuel, diesel No. 1, kerosene, and heating oil may require analysis as both GRO and DRO depending on the range of petroleum components present as measured in NWTPH-HCID.

(3) The following petroleum products are common examples of the heavy oil group: Motor oils, lube oils, hydraulic fluids, etc. Heavier oils may require the addition of an appropriate oil range standard for quantification.

(4) Mineral oil means non-PCB mineral oil, typically used as an insulator and coolant in electrical devices such as transformers and capacitors.

(5) The waste oil category applies to waste oil, oily wastes, and unknown petroleum products and mixtures of petroleum and nonpetroleum substances. Analysis of other chemical components (such as solvents) than those listed may be required based on site-specific information. Mixtures of identifiable petroleum products (such as gasoline and diesel, or diesel and motor oil) may be analyzed based on the presence of the individual products, and need not be treated as waste and unknown oils.

(6) When using Method A, testing soil for benzene is required. Furthermore, testing groundwater for BTEX is necessary when a petroleum release to groundwater is known or suspected. If the groundwater is tested and toluene, ethyl benzene or xylene is in the groundwater above its respective Method A cleanup level, the soil must also be tested for that chemical. When using Method B or C, testing the soil for BTEX is required and testing for BTEX in groundwater is required when a release to groundwater is known or suspected.

(7)(a) For DRO releases from other than home heating oil systems, follow the instructions for GRO releases in Footnote (6). (b) For DRO releases from typical home heating oil systems (systems of 1,100 gallons or less storing heating oil for residential consumptive use on the premises where stored), testing for BTEX is not usually required for either groundwater or soil. Testing of the groundwater is also not usually required for these systems; however, if the groundwater is tested and benzene is found in the groundwater, the soil must be tested for benzene.

(8) Testing is required in a sufficient number of samples to determine whether this chemical is present at concentrations of concern. If the chemical is found to be at levels below the applicable cleanup level, then no further analysis is required.

(9) Testing for n-hexane is required when VPH analysis is performed for Method B or C. In this case, the concentration of n-hexane should be deleted from its respective fraction to avoid double-counting its concentration. n-Hexane's contribution to overall toxicity is then evaluated using its own reference dose.

(10) Volatile fuel additives (such as dibromoethane, 1 - 2 (EDB) (CAS# 106-93-4) and dichloroethane, 1 - 2 (EDC) (CAS# 107-06-2)) must be part of a volatile organics analysis (VOA) of GRO contaminated groundwater. If any is found in groundwater, then the contaminated soil must also be tested for these chemicals.

(11) Methyl tertiary-butyl ether (MTBE) (CAS# 1634-04-4) must be analyzed in GRO contaminated groundwater. If any is found in groundwater, then the contaminated soil must also be tested for MTBE.

(12)(a) For automotive gasoline where the release occurred prior to 1996 (when "leaded gasoline" was used), testing for lead is required unless it can be demonstrated that lead was not part of the release. If this demonstration cannot be made, testing is required in a sufficient number of samples to determine whether lead is present at concentrations of concern. Other additives and blending compounds of potential environmental significance may need to be considered for testing, including: tertiary-butyl alcohol (TBA); tertiary-amyl methyl ether (TAME); ethyl tertiary-butyl ether (ETBE); ethanol; and methanol. Contact the department for additional testing recommendations regarding these and other additives and blending compounds. (b) For aviation gasoline, racing fuels and similar products, testing is required for likely fuel additives (especially lead) and likely blending compounds, no matter when the release occurred.

(13) Testing for carcinogenic PAHs is required for DRO and heavy oils, except for the following products for which adequate information exists to indicate their absence: Diesel No. 1 and 2, home heating oil, kerosene, jet fuels, and electrical insulating mineral oils. The carcinogenic PAHs include benzo(a)pyrene, chrysene, dibenzo(a,h)anthracene, indeno(1,2,3-cd)pyrene, benzo(k)fluoranthene, benzo(a)anthracene, and benzo(b)fluoranthene.

(14)(a) Except as noted in (b) and (c), testing for the noncarcinogenic PAHs, including the "naphthalenes" (naphthalene, 1-methyl-naphthalene, and 2-methyl-naphthalene) is not required when using Method A cleanup levels, because they are included in the TPH cleanup level. (b) Testing of soil for naphthalenes is required under Methods B and C when the inhalation exposure pathway is evaluated. (c) If naphthalenes are found in groundwater, then the soil must also be tested for naphthalenes.

(15) Testing for PCBs is required unless it can be demonstrated that: (1) The release originated from an electrical device manufactured for use in the United States after July 1, 1979; (2) oil containing PCBs was never used in the equipment suspected as the source of the release (examples of equipment where PCBs are likely to be found include transformers, electric motors, hydraulic systems, heat transfer systems, electromagnets, compressors, capacitors, switches and miscellaneous other electrical devices); or, (3) the oil released was recently tested and did not contain PCBs.

(16) Testing for other possible chemical contaminants may be required based on site-specific information.

(17) The analytical methods NWTPH-Gx, NWTPH-Dx, NWTPH-HCID, VPH, and EPH are methods published by the department of ecology and available on the department's internet web site: http://www.ecy.wa.gov/programs/tcp/cleanup.html.

Wash. Admin. Code § 173-340-900

Statutory Authority: RCW 70.105D.030(2). 07-21-065 (Order 06-10), § 173-340-900, filed 10/12/07, effective 11/12/07. Statutory Authority: Chapter 70.105D RCW. 01-05-024 (Order 97-09A), § 173-340-900, filed 2/12/01, effective 8/15/01.

Reviser's note: The brackets and enclosed material in the text of the above section occurred in the copy filed by the agency.