Ex Parte 5963329 et alDownload PDFBoard of Patent Appeals and InterferencesApr 25, 200690006185 (B.P.A.I. Apr. 25, 2006) Copy Citation THIS OPINION WAS NOT WRITTEN FOR PUBLICATION The opinion in support of the decision entered today (1) was not written for publication in a law journal and (2) is not binding precedent of the Board. UNITED STATES PATENT AND TRADEMARK OFFICE __________________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES __________________ Ex parte EDWARD W. CONRAD and DAVID P. PAUL Appeal No. 2006-0741 Reexamination Control No. 90/006,185 Patent No. 5,963,3291 HEARD April 5, 2006 Before MARTIN, LEE and MOORE, Administrative Patent Judges. LEE, Administrative Patent Judge. DECISION ON APPEAL This is a decision on appeal under 35 U.S.C. § 134 and § 306 from the examiner’s rejection of the patentee’s claims 1-14 and 16-28 in the patent reexamination proceeding. References relied on by the Examiner Raymond et al. (Raymond) “Metrology of subwavelength photoresist gratings using optical scatterometry,” Journal of Vacuum Science & Technology, B, Vol. 13, No. 4, July/August 1995, pp. 1484- 1495 1 Issued October 5, 1999, and based on application 08/961,929, filed October 31, 1997. Request for reexamination received January 10, 2002. The real party in interest is Nanometrics Incorporated. Moharam et al. (Moharam) “Diffraction characteristics of photoresist surface-relief gratings,” Applied Optics, Vol. 23, No. 18 (September 15, 1984), pp. 3214-3220. Case et al. (Case) 4,555,767 November 1985 Lochbihler et al. (Lochbihler I) “Characterization of highly conducting wire gratings using an electromagnetic theory of diffraction,” Optics Communications, Vol. 100, 1993, pp. 231-239. Lochbihler et al. (Lochbihler II) “Characterization of x-ray transmission gratings,” Applied Optics, Vol. 31, No. 7 (March 01, 1992), pp. 964-971. The Rejections on Appeal Claims 1-4, 8-13, 16, 17, 20, and 27-28 stand rejected under 35 U.S.C. § 103 as being unpatentable over Raymond and Moharam. Claims 5-7, 14, 18-19, and 21-26 stand rejected under 35 U.S.C. § 103 as being unpatentable over Raymond, Moharam, Case, Lochbihler I, and Lochbihler II. The Invention The invention is directed to a method and apparatus for determining the profile on a substrate having repeating structure by use of actual radiation diffraction and mathematical modeling. The intensity of diffracted illumination is compared with the predicted intensity of a model based on mathematical calculations. The independent claims are claims 1, 27 and 28, each of which is reproduced below: 1. A method of determining a profile, comprising the steps of: (a) providing a substrate having a repeating structure comprising a plurality of lines, said lines having substantially identical profiles; (b) illuminating said repeating structure with radiation wherein said radiation diffracts, said diffracted radiation having an intensity as a function of wavelength; Appeal No. 2006-0741 Reexamination Control No. 90/006,185 3 (c) measuring said intensity as a function of wavelength; (d) providing a model structure on a data processing machine, said model structure comprising a repeating structure on said substrate, said model structure comprising a model profile, wherein said model profile comprises an edge having more than one X position; (e) mathematically predicting a predicted diffracted radiation intensity when said model structure is illuminated with said radiation; and (f) comparing said predicted intensity with said measured intensity. 27. A method of determining the profile of a repeating structure comprising the steps of: (a) providing a substrate having a plurality of lines having substantially identical line profiles and spacings; (b) illuminating said lines with radiation having a range of wavelengths, wherein said radiation reflects with an intensity as a function of wavelength; (c) selecting a polarization state of said reflected radiation; (d) measuring the intensity of radiation reflected from said lines as a function of wavelength; (e) providing a model of the line profile and line spacing, wherein said model of the line profile comprises an edge having more than one X position; (f) mathematically predicting the intensity of radiation that would be reflected from the model as a function of wavelength; and (g) comparing the predicted intensity with the measured intensity; and Appeal No. 2006-0741 Reexamination Control No. 90/006,185 4 (h) adjusting the model and repeating steps (f) and (g) to improve agreement in said comparing step (g). 28. An apparatus for determining the profile of a line on a substrate, the apparatus comprising: a radiation source for illuminating the substrate with radiation, said substrate comprising a repeating structure, said repeating structure comprising a plurality of lines and spaces between said lines, said lines having substantially the same line profile, said spaces being substantially identical, the illuminating of the repeating structure for obtaining diffraction of said radiation, wherein said diffracted radiation has an intensity as a function of wavelength; a polarizer for selecting a single polarization state of diffracted light; a detector for measuring said intensity as a function of wavelength; a data processing machine comprising a computer model structure, said model structure comprising a model repeating structure on a model substrate, said repeating structure comprising a plurality of model lines and model spaces between said model lines, said model lines having substantially the same model line profile, each said model line comprising an edge having more than one X position, said model spaces being substantially identical, said data processing machine for mathematically predicting a predicted diffracted radiation intensity when said model structure is illuminated with said radiation source; said data processing machine further comprising means for comparing said predicted intensity with said measured intensity; and said data processing machine further comprising means for adjusting said model structure and for repeating said predicting and comparing steps to improve agreement in said comparing step. Appeal No. 2006-0741 Reexamination Control No. 90/006,185 5 Discussion A. The rejection of claims 1-4, 8-13, 16, 17, 20 and 27-28 under 35 U.S.C. § 103 over Raymond and Moharam The examiner applied Raymond as a primary reference disclosing the measuring of actual diffracted illumination from a substrate with repeating structures and a theoretical prediction of anticipated diffraction based on a mathematical algorithm. In Raymond, first the actual diffracted light fingerprint is measured (page 1485, column 2, lines 19-21 and 26-27). Thereafter, a diffraction model is used while varying each parameter over a certain range to calculate the theoretical diffraction over a parameter space (page 1485, column 2, lines 29-35). Based on the prediction data, those parameters that correspond to the actual diffraction fingerprint are determined (page 1485, column 2, lines 36-38). The appellant argues that the invention according to claim 1 applies broadband light as the source of illumination for the substrate (Brief at 2). The appellant argues that according to claim 27 the source of illumination has a range of wavelengths (Brief at 2). The appellant argues that according to all three independent claims 1, 27 and 28, the diffracted or reflected radiation has an intensity which is a function of wavelength and the diffracted or reflected radiation is measured as a function of wavelength (Brief at 2-3). The appellant states that Raymond does not teach applying a source radiation which has a range of wavelengths, or having any diffracted radiation which has an intensity as a function of wavelength, or measuring the diffracted radiation as a function of wavelength (Brief at 5). Appeal No. 2006-0741 Reexamination Control No. 90/006,185 6 At oral hearing the panel pointed out to counsel for the appellant that none of the three independent claims recites broadband illumination and that only claim 27 recites that the source illumination has a range of wavelengths, which may be construed as broadband illumination. The response from counsel for the appellant was that appellant’s claims 1 and 28 likewise require the source of illumination to have a range of wavelengths, and thus broadband illumination, because claims 1 and 28 recite that the applied illumination diffracts or reflects with an intensity that is a function of wavelength and that the diffracted illumination is measured as a function of wavelength. We agree. In light of the claim language to the effect that the diffracted or reflected radiation has an intensity which is a function of wavelength and that the diffracted or reflected radiation is measured as a function of wavelength, the claims are properly interpreted as requiring source illumination which has a range of wavelengths. If not, then the diffracted or reflected radiation could not reasonably be deemed as “measured as a function of wavelength.”2 There is no dispute between the examiner and the appellant in that regard. Single wavelength source illumination such as the laser light of Raymond is not sufficient for meeting 2 We recognize that claim 12 depends ultimately from claim 1 and further requires that the radiation has a range of wavelengths, which additional requirement is an indication that claim 1 does not by itself require the radiation to have a range of wavelengths per application of the doctrine of claim differentiation. However, the doctrine is not a controlling factor for claim interpretation. Here, the language of claim 1 compels a conclusion otherwise. Appeal No. 2006-0741 Reexamination Control No. 90/006,185 7 the appellant’s claims. The examiner recognized that, and attempted to make up the deficiency of Raymond by relying on disclosure of the Moharam reference. But the examiner’s reliance on Moharam is misplaced. According to the examiner, Moharam discloses that diffraction intensity is measured as a function of wavelength, employs a similar rigorous coupled wave analysis and is within the same field of endeavor as Raymond (Answer at 5, lines 4-10). As is correctly noted by the appellant, however, that part of Moharam evidently relied on by the examiner states (Moharam, p. 3219, column 2, lines 13-17): The diffraction characteristics as a function of (1) angle of incidence, (2) polarization, and (3) wavelength have all been measured experimentally and calculated theoretically using a surface-relief modulated half-space model. Good general agreement is found between theory and experiment. That disclosure, however, reveals only that diffraction characteristics depend on the angle of incidence of the source illumination, on the polarization of the source illumination, and on the wavelength of the source illumination. As is stated in the introduction portion of Moharam (page 3214, column 2, lines 3-9): This study compares theoretically calculated and experimentally measured angular selectivities (angle of incidence dependence of the diffraction efficiency at a fixed wavelength) and wavelength selectivities (wavelength dependence of the diffraction efficiency for a fixed angle of incidence) of these gratings for both TE and TM polarizations. The Moharam reference studies how diffraction results change based on variations in the angle of incidence while the wavelength is fixed, and on variations in the wavelength of the source illumination while the angle of incidence is fixed, for both TE and TM polarizations of the Appeal No. 2006-0741 Reexamination Control No. 90/006,185 8 incident light. Angular and wavelength selectivities are determined. As is described in Moharam on page 3217, column 2, lines 4-8: Appeal No. 2006-0741 Reexamination Control No. 90/006,185 9 The angular and wavelength selectivities of a grating are measures of the sensitivity of the diffraction to changes in the angle of incidence (with the wavelength fixed) and to changes in the wavelength (with the angle of incidence fixed). Moharam discloses the use of a source illumination including a range of wavelengths and the measuring of diffraction intensity as a function of wavelength. But it is for determining diffraction sensitivities to differences in the wavelength of the source illumination, and not a blanket teaching that source illumination having a range of wavelengths be applied and diffraction intensity be measured as a function of wavelength whenever diffraction of source illumination from a substrate is measured. Moreover, as is pointed out by the appellant, in Moharam while the angle of incidence is varied, the wavelength of the incident illumination remains fixed, and while the wavelength of the incident illumination is varied, the angle of incidence remains fixed (Moharam, page 3214, column 2, lines 3-9; page 3217, column 2, lines 4-8). Moharam teaches that the intensity of the diffracted radiation depends on the wavelength of the source illumination and not that source illumination including a range of wavelengths should be applied and that the resulting diffraction should be measured as a function of wavelength in any particular type of situation other than for measuring diffraction efficiencies. The foregoing is consistent with the following paragraph contained in the declaration of Mircea Dusa submitted by the appellant on July 21, 2003, and attached to the appellant’s brief: 8. Moharam relates to the examination of diffraction characteristics of photoresist diffraction gratings. Moharam studies the angular and wavelength selectivities of diffraction gratings by measuring the sensitivity of the diffraction to changes in the angle of incidence (with the Appeal No. 2006-0741 Reexamination Control No. 90/006,185 10 wavelength fixed) and to changes in the wavelength (with the angle of incidence fixed). See, p. 3217, second column, 1st full paragraph, and see Abstract. Moharam also studies the sensitivity of the diffraction gratings to the polarization (TE or TM) of the incident light. See, p. 3217, paragraph bridging 1st and 2nd columns. The examiner has articulated no basis to discredit the above-quoted testimony of Mircea Dusa. Raymond discloses a system and method for determining the widths and overall profiles of dielectric grating lines by measuring the intensity of diffracted laser light from the sample substrate over a specified range of incident beam angles (Raymond, page 1484, Introduction). As is determined correctly by the examiner (Answer at 4), Raymond discloses comparing the predicted diffraction intensity over the range of incident beam angles as calculated through a mathematical algorithm applied to a model to the actual measured diffraction intensity (Raymond, page 1485, column 2, lines 9-49). But the wavelength of incident illumination is fixed and the diffraction intensity is not measured as a function of wavelength. Raymond’s system and method depend on measuring the diffraction intensity as a function of a varying incident angle. As is stated in Raymond on page 1485, column 2, lines 46-54: The sample is mounted on a stage that permits it to rotate. Since the beam itself is fixed, this rotation changes the angle of incidence on the sample. Using grating Eq. (1), the detector arm of the scatterometer is able to follow any diffracted order as this angle is varied. The intensity of a particular diffraction order as a function of incident angle, which is known as 2-t plot or scatter “signature,” is then downloaded to a computer, where the analysis can begin. The wavelength of Raymond’s incident laser is not changed when the incident angle is changed. Similarly, in Moharam, as is discussed above, while the angle of incidence is changed, the wavelength of the source illumination stays fixed. Appeal No. 2006-0741 Reexamination Control No. 90/006,185 11 Obviousness is a question of law based on findings of underlying facts relating to the prior art, the skill of the artisan, and objective considerations. See Graham v. John Deere Co., 383 U.S. 1, 17, 148 USPQ 459, 467 (1966). To establish a prima facie case of obviousness based on a combination of the content of multiple references, there must be a teaching, suggestion, or motivation in the prior art to make the specific combination that was made by the applicant. In re Raynes, 7 F.3d 1037, 1039, 28 USPQ2d 1630, 1631 (Fed. Cir. 1993); In re Oetiker, 977 F.2d 1443, 1445, 24 USPQ2d 1443, 1445 (Fed. Cir. 1992). As discussed in Interconnect Planning Corp. v. Feil, 774 F.2d 1132, 1143, 227 USPQ 543, 551 (Fed. Cir. 1985), it is the prior art itself, and not the applicant's disclosure, that must establish the obviousness of the combination. The examiner has not articulated any reasonable teaching, suggestion, or motivation for one with ordinary skill in the art, in light of the Moharam reference, to apply in Raymond source illumination including a range of wavelengths and then measuring the diffracted or reflected illumination as a function of wavelength. The rigorous diffraction model and the statistical prediction algorithm used in Raymond are based on varying the incident angle with a fixed wavelength and not the inverse, i.e., multiple wavelength of incident illumination and a fixed incident angle. Also, Moharam does not disclose the application of incident illumination with multiple wavelengths and measuring the resulting diffraction as a function of wavelength in any particular application except for determining the sensitivity of diffraction to wavelength, and even then, it would be for a fixed incident angle of illumination. Based on the disclosure of Appeal No. 2006-0741 Reexamination Control No. 90/006,185 12 Raymond and Moharam, as presented by the examiner, we do not see how one with ordinary skill in the art would recognize that something useful or beneficial would result by applying source illumination with a range of wavelengths in Raymond and measuring the resulting diffraction as a function of wavelength. That rationale has not been adequately established by the examiner. We do not disagree that for determining the selectivity of diffracted radiation to the wavelength of the incident light, Moharam discloses applying, with a fixed incident angle, source illumination including a range of wavelengths and thereafter measuring the resulting diffraction as a function of wavelength. However, that disclosure is a long way from being a reasonable teaching, suggestion, or motivation for applying in Raymond a source illumination which includes a range of wavelengths and measuring in Raymond the resulting diffraction as a function of wavelength. Raymond’s system and method depend on a varying incident angle and a fixed wavelength for its source illumination. Claim 27 further requires the step of selecting a polarization state of the reflected radiation. Claim 28 further recites a polarizer for selecting a single polarization state of diffracted light. The examiner attempted to meet these requirements by relying on Raymond’s disclosure that TE polarized laser is used as the source illumination and on Moharam’s disclosure that changes in diffraction efficiency based on incident angle and wavelength of the source illumination are more acute for incident light with TE polarization than incident light with TM polarization (Answer at 10-11). The comparison Appeal No. 2006-0741 Reexamination Control No. 90/006,185 13 is inappropriate and inadequately explained because the polarization referred to in Raymond and in Moharam is with regard to the incident illumination. The examiner has not shown that either reference teaches selecting a polarization state of the reflected radiation as is recited in claim 27 or a polarizer for selecting a single polarization state of diffracted light as is recited in claim 28. For all of the foregoing reasons, the rejection of claims 1-4, 8-13, 16, 17, 20, and 27-28 over Raymond and Moharam cannot be sustained. We have no need to consider objective evidence of nonobviousness submitted by the appellant with regard to alleged commercial success. B. The rejection of claims 5-7, 14, 18-19, and 21-26 under 35 U.S.C. § 103 as unpatentable over Raymond, Moharam, Case, Lochbihler I, and Lochbihler II As applied by the examiner, the deficiencies of Raymond and Moharam is not made up by the disclosure of Case, Lochbihler I, and Lochbihler II. Accordingly, the rejection of dependent claims 5-7, 14, 18-19, and 21-26 also cannot be sustained. Conclusion The rejection of claims 1-4, 8-13, 16, 17, 20, and 27-28 under 35 U.S.C. § 103 as unpatentable over Raymond and Moharam is reversed. The rejection of claims 5-7, 14, 18-19, and 21-26 under 35 U.S.C. § 103 as unpatentable over Raymond, Moharam, Case, Lochbihler I and Lochbihler II is reversed. Appeal No. 2006-0741 Reexamination Control No. 90/006,185 14 REVERSED /John Martin/ ) JOHN MARTIN ) Administrative Patent Judge ) ) ) ) /Jameson Lee/ ) BOARD OF PATENT JAMESON LEE ) APPEALS Administrative Patent Judge ) AND ) INTERFERENCES ) ) /James T. Moore/ ) JAMES T. MOORE ) Administrative Patent Judge ) Appeal No. 2006-0741 Reexamination Control No. 90/006,185 15 By First Class Mail Attorney for the appellant: Michael J. Halbert Silicon Valley Patent Group LLP 2350 Mission College Boulevard. Suite 360 Santa Clara, California 95054 Copy with citationCopy as parenthetical citation